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首次报道了2-(2'-羟基苯基)苯并f唑(HBO)分子在若干高分子固体膜中的电子光谱和激发态分子内质子转移(ESIPT)的特性,并与溶液体系中的相应特性进行了比较,揭示了新的吸收和发射带,并讨论了高分子基质对这些特性的影响和作用机制。
The electronic spectra and intramolecular proton transfer (ESIPT) properties of 2- (2’-hydroxyphenyl) benzoxazole (HBO) molecules in several polymer solid films were reported for the first time. The corresponding properties were compared, revealing new absorption and emission bands, and discussing the effect of the polymer matrix on these properties and the mechanism of action.