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Pt/Au Schottky contacts were fabricated on modulation-doped Alo.22GaNo. 7s/GaN heterostructures. Some dif-ferent pre-deposition surface treatments were used to prevent the formation of the native oxide layer on the Alo.22GaNo.78 surface. X-ray photoelectron spectroscopy measurements indicate that the pre-deposition surface treatment with boiling (NH4)2S solution can remove the native oxide layer on the Alo.22Gao.7sN surface effec-tively. The highest Schottky barrier height of 1.13eV was obtained on the (NH4)2S-treated Al0.22GaNo. 78/GaN heterostructure.