Temperature-controlled Hydrothermal Synthesis of Copper（Ⅰ or Ⅱ） Coordination Polymers via a Variety

• 作 者: QU Xue-jian WANG Shuang ZHANG
• 机 构: StateKeyLaboratoryofInorganicSynthesisandPreparativeChemistry
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2012年4期
• 关键词: 配位聚合物 水热合成 温度控制 铜离子 单晶X-射线衍射 管状结构 一维链 BTA Hydrothermal synthesis Coordination mo
• 基金项目: Supported by the National Natural Science Foundation of China（Nos.20701015,21071059,20788101）

Two 1D coordination polymers Cu2I(C6N3H4)2(1) and CuⅡ(C6N3H4)2·H2O(2) based on benzotriazole(Bta) were hydrothermally synthesized by controlling the crystallization temperature.Single-crystal X-ray diffraction(XRD) analyses reveal that compound 1 is