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Cyclic voltammetry (CV) and single-step chronocoulometry wereused to study the interaction of [Ru(phen)2dppz]2+ (phen=l,10-phenanthroline; dppz=dipyrido[3,2-a:2′,3′-c]phenazine) with herring sperm DNA. The addition of DNA caused a diminution in the peak c