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测定了MMNi5基贮氢合金的电极特性。用快淬法制成的MM(0.9)Ti(0.1)Ni(3.9)Mn(0.4)Co(0.4)Al(0.3)贮氢合金电极的循环寿命和快速放电能力显著提高,其300次充放电循环后电容量仅下降18%,这与合金中微晶组织的形成有关,而感应熔炼制成的MM(0.9)Ti(0.1)Ni(3.9)Mn(0.4)Co(0.4)Al(0.3)贮氢合金电极200次循环后电容量下降39%,经1000℃3h退火后,其300次循环后电容量下降为27%。
The electrode characteristics of MMNi5-based hydrogen storage alloy were measured. The cycle life of MM (0.9) Ti (0.1) Ni (3.9) Mn (0.4) Co (0.4) Al (0.3) The discharge capacity of the alloy was significantly increased. The capacity decreased only 18% after 300 charge and discharge cycles, which was related to the formation of microcrystalline microstructure in the alloy. However, the MM (0.9) Ti (0.1) Ni (3.9) The capacitance of Mn (0.4) Co (0.4) Al (0.3) hydrogen storage alloy electrode decreases by 39% after 200 cycles, and after 300 cycles of annealing at 1000 ℃ for 3h Capacity dropped to 27%.