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从室温至380K测量了热致液晶4己氧基苯甲酸4氰基苯酯(CPHOB)的氢核磁共振谱.其固态至向列相的转变温度Tsn=347K,向列相至各向同性液体的转变温度Tni=359K.得到了液晶态有序参数的温度关系.讨论了氢核磁共振的自旋晶格弛豫机制.
The hydrogen nuclear magnetic resonance spectrum of the 4-cyanoacetophenone 4-cyanobenzoate (CPHOB) was measured from room temperature to 380K. Its transition temperature from solid to nematic phase is Tsn = 347K, and the transition temperature from nematic phase to isotropic liquid is Tni = 359K. The temperature dependence of ordered parameters of the liquid crystal is obtained. The spin lattice relaxation mechanism of hydrogen nuclear magnetic resonance is discussed.