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胶束体系的一个突出性质是其对有机化合物的增溶能力以及这种能力对各种添加剂的敏感性.研究中常涉及到的添加剂是中性电解质.曾报道顺磁性三价镧系离子对SDS胶束中三线态自由基对的反应有电解质效应及外磁场依赖的内磁场效应的协同效应.后者有加速三线态自由基对从T_+和T_-态向T_0及S_0态弛豫以抵消外磁场效应的作用.在镧系离子族中,钆离子(Gd~(3+))以其具有的7个未成对电子而具有最大的内磁场效应. 虽然有不少文章对于电解质的添加剂效应进行了探讨,但对于添加剂对胶束性质影响的
One salient property of the micellar system is its ability to solubilize organic compounds and the sensitivity of this ability to various additives. The additive most commonly used in this study is neutral electrolytes. It has been reported that paramagnetic trivalent lanthanide ions are sensitive to SDS The response of the triplet free radical pairs in the micelles has the synergistic effect of the electrolyte effect and the internal magnetic field dependence of the external magnetic field, which accelerates the relaxation of the triplet state radicals T_0 and S_0 from T_ + and T_-states to cancel In the Lanthanide family, gadolinium ion (Gd ~ (3+)) has the largest internal magnetic field effect due to its seven unpaired electrons.Although there are many articles on the additive effect of electrolyte The effects of additives on micelle properties were investigated