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A new ET based cation radical salt, α'-(ET)2C6H4(SO3)2 (ET = bis(ethylenedithio) tetrathiafulvalene) has been synthesized by oxidative electro-crystallization and the crystal structure determined to be in monoclinic system, P2/n space group. Its resistivity-temperature curve shows a semi-conductive behavior with a discontinuation at about 150K.