【摘 要】
：
合成了标题化合物。该化合物的分子式[Ni(C5H5N)2(C7H6O2N)2]H2O(C24H24N4NiO3),分子量475.18,采用单色的MoKα (λ = 0.71073 u001f)射线测定,共收集7408个数据,其中独立衍
【机 构】
：
广西师范大学化学化工系,桂林工学院,桂林工学院,广西师范大学化学化工系,香港理工大学应用生物与化学科学系 桂林541004,桂林541004,桂林541004,桂林541004,香港
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合成了标题化合物。该化合物的分子式[Ni(C5H5N)2(C7H6O2N)2]H2O(C24H24N4NiO3),分子量475.18,采用单色的MoKα (λ = 0.71073 u001f)射线测定,共收集7408个数据,其中独立衍射点2567个(Rint = 0.0272),I > 2s(I)可观测点数1926个,结果表明该化合物属单斜晶系, 空间群C2/c其晶胞参数为: a = 14.466(2),b = 12.193(2),c = 14.072(2) u001f;β = 116.229(2)°,V = 2226.6(5) u001f3,Z = 4,Dc = 1.418 g/cm3 ,μ = 0.905 mm-1,F(000) = 992. 2个水杨醛亚胺各提供2个配位原子参与配位,2个吡啶各提供1个配位原子参与配位,该配合物是六配位的八面体构型,同时讨论了该体系中不同配位原子的配位能力的差异。
The title compound was synthesized. The compound has a molecular formula of NiCe5H5N2 (C7H6O2N) 2] H2O (C24H24N4NiO3) and a molecular weight of 475.18. A total of 7408 data were collected by monochromatic MoKa (λ = 0.71073 u001f) (Rint = 0.0272) and I> 2s (I) were 1926. The results showed that the compound belongs to the monoclinic system with space group C2 / c with a = 14.466 (2) and b = 12.193 (4) D = 1.418 g / cm3, μ = 0.905 mm-1, F (0002), c = 14.072 ) = 992. Two salicylaldimines each provide two coordination atoms to participate in the coordination, and two pyridine each provide one coordination atom to participate in the coordination. The coordination complex is a hexacoordinated octahedral configuration and the Differences in coordination ability of different coordination atoms in this system.
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