Preparation and characterization of polymer-clay nanocomposite films

来源 :Science in China(Series B:Chemistry) | 被引量 : 0次 | 上传用户:hhkjtest
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Polymer/clay nanocomposite films were prepared by means of electrodeposition of aqueous suspension including cathodic electrophoretic acrylic resin (CEAR) and Na+-montmorillonite (NMMT). Studies of XRD,SEM and TEM indicated well-dispersed NMMT platelets in the films prepared. The ideal dispersity achieved was thought to be the result of aqueous compatibility between CEAR molecules and NMMT platelets and the result of the water-involved process as well. The modulus and strength of the polymer/clay nanocomposite coatings tested by tensile testing and nano-indentation were effectively improved compared to those of the virgin CEAR film. In addition,the adhesion strength,flexibility and water-resistance represented by Chinese national standard (GB) kept the best grades. Polymer / clay nanocomposite films were prepared by means of electrodeposition of aqueous suspension including cathodic electrophoretic acrylic resin (CEAR) and Na + -montmorillonite (NMMT). Studies of XRD, SEM and TEM showed well-dispersed NMMT platelets in the films prepared. The ideal dispersity achieved was thought to be the result of aqueous compatibility between CEAR molecules and NMMT platelets and the result of the water-involved process as well. The modulus and strength of the polymer / clay nanocomposite coatings tested by tensile testing and nano-indentifation were effectively improved compared to those of the virgin CEAR film. In addition, the adhesion strength, flexibility and water-resistance represented by Chinese national standard (GB) kept the best grades.
其他文献
塑料建材的发展趋势解挺朱元吉尹延国王晓枫目前我国塑料建材的进一步发展,一要注重提高现有产品的质量和档次,二要着力开发有广泛应用价值的新产品,我们认为,今后我国的建筑塑料
FMZ型高效防火阻燃剂江都市新城化工厂与南开大学合作,共同研制开发成功一种新型阻燃材料——FMZ型高效防火阻燃剂,现已投入批量生产。该阻燃剂为白色粉状固体,易溶于水,水溶液无色透明
一、教育中融入多元文化教育的目的基于国内外专家对多元文化教育内容的界定和地理学科的特点,本文认为在技工教育中融入多元文化教育的目的是:1.了解多元文化知识多元文化知
“创新是一个民族进步的灵魂,是国家兴旺发达的不竭动力。”当今世界是一个竞争的世界,如果不能创新,不去创新,一个民族就难以发展起来,难以屹立于世界民族之林。因此,创新意
梅氏冲击试样槽的加工,如果采用刨或铣的方法,都会因留有横向加工刀痕而影响冲击试验结果。我们经过多次的试验改进了一种钻槽工具,这种工具不仅能保证加工质量,而且便于操
一、前言 12型迴转弯曲疲劳试验机是目前各厂、各研究单位广泛采用的一种疲劳試驗机。这种試驗机的負載系統是靠附加砝碼及吊挂砝碼的支架等零件的重量构成,系統初载一般是
我国优秀的传统文化艺术饮誉世界,尤以古陶瓷深受世人青睐。因其具有独特的历史风貌,并蕴含极深的文化内涵,国内外文物专家、学者倾其毕生精力,广为探索、搜集、珍藏和专心
2004年是高考语文命题出现重大转折的一年。从这一年开始,许多省(市)自主命题,高考试题由此打破了“全国卷”几乎一统天下的格局,呈现出百花齐放的新气象。通观这些试题,虽各
教师都比较重视和讲究课堂教学的精彩开头——导入。然而,与导入相对应的每堂课的收尾阶段却往往被忽视。其实,课堂教学的结尾和导入一样重要,因为结尾往往起着温故而知新的作用。优秀的课堂教学结尾是巩固课堂教学的重要环节,是衔接新旧知识、贯通前后内容的纽带,是从课内到课外、由知识向能力过渡的桥梁,是启迪思考和开发智力的良机。课堂教学的结尾是一种艺术,需要教师重视和创新。根据自己的教学实践,笔者总结了以下几种
TiO2 nanotube (NT) arrays have been prepared by anodic oxidation of a Ti sheet,and carbon-deposited TiO2 NT arrays have been prepared by annealing TiO2 NT array