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用ＴＰＤ、ＴＰＳＲ和ＣＯ氧化活性测定等技术研究了ＣＯ在Ｐｔ／Ａｌ２Ｏ３和含有ＺｒＯ２的样品上的吸脱附行为、表面反应及催化氧化活性。结果表明，在Ｐｔ／Ａｌ２Ｏ３中浸渍法添加ＺｒＯ２或掺杂ＺｒＯ２后，催化剂的氧化活性均明显提高；ＣＯ－ＴＰＳＲ的实验结果表明，程序升温脱附过程中ＣＯ在氧化态Ｐｔ催化剂上与催化剂的表面氧发生氧化反应，而在还原态Ｐｔ催化剂上主要发生歧化反应；并发现在ＣＯ－ＴＰＳＲ过程中程脱物ＣＯ２的脱附量及脱附峰温次序与对ＣＯ的催化氧化活性也有一致的对应关系。
The adsorption and desorption behaviors, surface reactions and catalytic oxidation activities of CO on Pt / Al2O3 and ZrO2-containing samples were investigated by TPD, TPSR and CO oxidation assay. The results show that the oxidation activity of the catalyst increases obviously when the ZrO2 or ZrO2 is added into the Pt / Al2O3 impregnation method. The CO-TPSR experimental results show that during the temperature-programmed desorption process, The surface oxygen oxidation reaction, and in the reduction of Pt catalyst mainly disproportionation reaction; and found in the process of CO-TPSR desorption CO2 desorption amount and desorption peak temperature order and the catalytic activity of CO oxidation of the corresponding relationship.