Syntheses and Crystal Structures of Two New Mercury（Ⅱ） Complexes with Double Betaine Ligands

• 作 者: LI Yan XU Hu ZHENG Fa-Kun WANG
• 机 构: DepartmentofChemistry,StateKeyLaboratoryofStructuralChemistry
• 出 处: 结构化学
• 发表日期: 2011年6期
• 关键词: 晶体结构 氯化汞 甜菜碱 配合物 配体 合成 吡啶环 衍射技术 mercury（Ⅱ） compound double betaine crystal struc
• 基金项目: financially supported by the National Natural Science Foundation of China （20871115）, Fujian Provincial Key Laboratory of Nanomaterials （NM10-06）

Reaction of HgCl2 and double betaine ligands in water at about 80 ℃ yielded two new Hg(Ⅱ) complexes,[Hg(L1)Cl2]·H2O 1 and [Hg2(L2)Cl4]·3HgCl2 2(L1 = 1,3-bis(pyridinio-4-carboxylato)-propane,L2 = 1,4-bis(pyridinio-4-carboxylato)-1,4-dimenthylbenz