NazZnSnzS6： A mixed-metal thiostannate with large second-harmonic generation response activated by

• 作 者: LI GuangMao WU Ku LIU Qiong YA
• 机 构: KeyLaboratoryofFunctionalMaterialsandDevicesforSpecialEnvironments,UniversityofChineseAcademyofScien
• 出 处: 中国科学：技术科学英文版
• 发表日期: 2017年10期
• 关键词: 锡化合物 四面体 二次谐波产生 非线性光学效应 三维结构 反应 金属 混合 Na2ZnSn2S6 nonlinear optical infrared s
• 基金项目: This work was supported b.v the Western Light Foundation ofChinese Acad- emy of Scienees （Grant No. XBBS201318）, the National Natural Science Foundation of China （Grant Nos. 51402352, 51425206 ＆ 91622

A sodium zinc thiostannate Na_2ZnSn_2S_6 is reported with its interesting structural features and property characteristics. It crystallizes in the polar space %xou^Fddl(No. 43) with the unit cell parameters of a=12.945(3),b=23.556(5), c=7.2774(15)and Z