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This work is aimed to synthesize new type ceramic materials: Pb1-2XSmxNdx[(Zr0,55Ti0,45)1-0.02,0.01(Y2/3,Mo1/3),0.01 (Y2/3,Ni1/3)]O3 of structure perovskite in the presence of the doping agents: NiO, Sm2O3, Y2O3, Nd2O3 and MoO3 near the morphotropic phase