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参考文献合成了N.N'-二(α-羟基苯亚甲基)肼(简记为H2Sala2)及其Co(Ⅱ)的配合物(简记为[Co(Sala2)]·2H2O).其化学组成及结构由元素分析、红外光谱和核磁共振谱所证实.配合物的载氧实验表明.在常温常压下,1mol的[Co(Sala2)]·2H2O可吸收约1.33mol的氧气,吸氧量随吸氧次数的增加而逐渐下降.
The reference synthesis of N N’-bis (α-hydroxybenzylidene) hydrazine (abbreviated as H2Sala2) and its Co (Ⅱ) complex (abbreviated as [Co (Sala2)] · 2H2O). Its chemical composition and structure are confirmed by elemental analysis, infrared spectroscopy and nuclear magnetic resonance spectroscopy. Oxygen-carrying complexes show that. At normal temperature and pressure, 1mol of [Co (Sala2)] 2H2O can absorb about 1.33mol of oxygen, and the amount of oxygen decreased gradually with the increase of oxygen absorption.