Chiral cyanide-bridged 1D FeⅢ-MnⅢ heterobimetallic chains： Synthesis, structures and magnetic prope

• 作 者: YAO MinXia ZHENG Qi GAO Feng L
• 机 构: StateKeyLaboratoryofCoordinationChemistry
• 出 处: 中国科学：化学英文版
• 发表日期: 2012年6期
• 关键词: 铁磁相互作用 磁学性质 手性 合成 双核 锰 磁性联轴器 氰桥 chiral complexes cyanide ligands chain compoun
• 基金项目: financially supported by the Major State Basic Research Development Program (2011CB808704),the National Natural Science Foundation of China (91022031)

Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,R)-Salphen)Fe(Tp)(CN)3]n (1) and [Mn((S,S)-Salphen)Te(Tp)(CN)3]n (2) (Salphen = N,N'-1,2- diphenyl ethylenebis (salicylideneiminato