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The title compound {Mo[S2CN( C2H5)2]4+1{MoCl6}-1 was synthesized,and its crystal structure was determined by X-ray diffraction.It is nionoclinic,space group P21/a with a=14.761(6)A b=16.012(6)A,c=17.108(9)A,β=102.63(4) and Z=4.The coordinates of a molybdenum atom were deduced from the Patterson function,and parameters of other atoms were found from successive Fourier syntheses.The block-diagonal least-siuares refinement for all alons gave final residual factors R=0.0908,Rw=0.0761.
The title compound {Mo [S2CN (C2H5) 2] 4 + 1 {MoCl6} -1 was synthesized, and its crystal structure was determined by X-ray diffraction. It is nionoclinic, space group P21 / a with a = 14.761 ) A b = 16.012 (6) A, c = 17.108 (9) A, β = 102.63 (4) and Z = 4. The coordinates of a molybdenum atom were deduced from the Patterson function, and parameters of other atoms were found from successive Fourier syntheses. The block-diagonal least-siuares refinement for all alons gave final residual factors R = 0.0908, Rw = 0.0761.