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Two novel one- and two-dimensional network structure bismuth(III) complexes with N,N-di(2-hydroxylethyl)- aminodithiocarboxylate, {Bi[S2CN(C2H4OH)2]2[1,10-Phen]2(NO3)}3H2O (1) and {Bi[S2CN(C2H4OH)2]3}2 (2) were synthesized. Their crystal and molecular structures were determined by X-ray single crystal diffraction analysis. The crystal 1 belongs to monoclinic system with space group C2/c, a=1.6431(7) nm, b=2.4323(10) nm, c=1.2646(5) nm, =126.237(5)o, Z=4, V=4.076(3) nm3, Dc=1.757 Mg/m3, =4.598 mm-1, F(000)=2156, R=0.0211, wR=0.0369. The structure shows a distorted square antiprism configuration with eight-coordination for the central Bi atom. The one-dimensional chain structure was formed by H-bonding interaction between hydroxyl group of N,N-di(2-hydroxylethyl)aminodithiocarboxylate ligands and crystal water. The crystal 2 belongs to monoclinic system with space group P2(1)/c, a=1.1149(4) nm, b=2.1274(8) nm, c=2.2107(8) nm, =98.325(8), Z=4, V=5.188(3) nm3, Dc=1.920 Mg/m3, =7.315 mm-1, F(000)=2944, R=0.0565, wR=0.0772. The structure shows a distorted square antiprism configuration with eight-coordination for the central Bi atoms. The two-dimensional network structure was formed by H-bonding interaction between adjacent molecules.
Two novel one and two dimensional network structure bismuth (III) complexes with N, N-di (2-hydroxylethyl) -aminodithiocarboxylate, {Bi [S2CN (C2H4OH) 2] Their crystal and molecular structures were determined by X-ray single crystal diffraction analysis. The crystal 1 belongs to monoclinic system with space group (3H) (1) and {Bi [S2CN (C2H4OH) 2] 3} 2 = 3.2643 (10) nm, c = 1.2646 (5) nm, = 126.237 (5) o, Z = 4, V = 4.076 (3) nm3, Dc = 1.757 Mg / m3, = 4.598 mm-1, F (000) = 2156, R = 0.0211, wR = 0.0369 The structure shows a distorted square antiprism configuration with eight-coordination for the central Biatom formed by H-bonding interaction between hydroxyl group of N, N-di (2-hydroxylethyl) aminodithiocarboxylate ligands and crystal water. The crystal 2 belongs to monoclinic system with space group P2 (1) / c, a = 1.1149 , b = 2.1274 (8) nm, c = 2.2107 (8) nm, = 98.325 (8), Z = 4, V = 5.188 (3) nm3, Dc = 1.920 Mg / m3, F (000) = 2944, R = 0.0565, wR = 0.0772. The structure shows a distorted square antiprism configuration with eight-coordination for the central Bi atoms. The two-dimensional network structure was formed by H-bonding interaction between adjacent molecules.