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以氯化锌、对苯二甲酸和4, 4′-联吡啶为原料, 采用溶剂热合成法成功合成Zn (bdc) 2 (4, 4′-bipy) 配合物 (bdc=对苯二甲酸根, bipy=联吡啶), 采用元素分析法、红外光谱法 (IR) 、热重分析法 (TGA) 和粉末X-射线衍射法 (PXRD) 对其结构测定和表征.标题配合物通过C-H…O氢键连接形成三维超分子结构.在室温条件下, 标题配合物表现出较强的荧光性能, 其荧光性能主要来自于配体到配体的跃迁, 可以作为具有潜在发展能力的荧光光学材料.“,”One new coordination polymer, Zn (bdc) 2 (4, 4′-bipy) (bdc=terephthalicacid, bipy=bipyridine), based on ZnCl2, terephthalic acid and 4, 4′-bipyridine was solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrometry (IR), elemental analysis, power X-ray diffraction (PXRD) and thermogravimetric analysis (TGA).The title compound was linked into three-dimensional (3 D) supramolecular structure by C-H…O hydrogen bonds.The title compound demonstrates fluorescent property, which mainly comes from the transition from the ligand to ligand.The title compound may be an optical material with potential development capability.