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有机小分子电极氧化过程中的振荡现象已作为非线性电极过程复杂体系动力学的一个典型实验进行了研究[1,2].Shel等报道了有机小分子电极氧化循环伏安曲线的振荡[3~5],表面上吸附物质或膜的生成与消耗是导致振荡乃至混沌行为发生的原因.在低NaOH浓度时...
Oscillation in the oxidation of small organic molecules has been investigated as a typical experiment for the kinetics of complex systems in nonlinear electrode processes [1,2]. Shel et al. Reported the oscillation of the cyclic voltammetry curve of organic small molecule oxidation [3-5]. The formation and depletion of adsorbed material or membrane on the surface of the electrode lead to oscillation and even chaos. At low NaOH concentration ...