A new strategy for the synthesis of unsymmetrical phosphotriesters

• 作 者: 胡军 丁贻祥
• 机 构: Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , Shanghai 200032 , China,Shang
• 出 处: Chinese Journal of Chemistry
• 发表日期: 2000年02期
• 关键词: alcohol esters afford phenol iodine converted alkyl remove phospho condensation

A new strategy for the synthesis of unsymmetrical phosphotri-esters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmitrical triesters in the presence of iodine in high yields under exceptionally mild conditions.

A new strategy for the synthesis of unsymmetrical phosphotri-esters was reported: which then reacted with the second alcohol or phenol to afford required unsymmitrical triesters in the presence of iodine in high yield under exceptionally mild conditions .