用NRTL方程推算高压汽液平衡并同时描述过量焓

来源 :中国化学工程学报(英文版) | 被引量 : 0次 | 上传用户:iqwanifir
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The non-random two liquids (NRTL) equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies (hE) and vapour-liquid equilibria (VLE) and the VLE prediction from hE data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of hE and VLE data and the VLE extrapolation are analysed in detail.
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