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Surface passivation with organic materials is one of the most effective and popular strategies to improve the stability and efficiency of perovskite solar cells (PSCs).However,the secondary bonding formed between organic molecules and perovskite layers is still not strong enough to protect the perovskite absorber from degradation initialized by oxygen and water attacking at defects.Recently,passivation with inorganic materials has gradually been favored by researchers due to the effectiveness of chemical and mechanical passivation.Lead-containing substances,alkali metal halides,transition elements,oxides,hydrophobic substances,etc.have already been applied to the surface and interfacial passivation of PSCs.These inorganic substances mainly manipulate the nucleation and crystallization process of perovskite absorbers by chemically passivating defects along grain boundaries and surface or forming a mechanically protective layer simultaneously to prevent the penetration of moisture and oxygen,thereby improving the stability and efficiency of the PSCs.Herein,we mainly summarize inorganic passivating materials and their individual passivation principles and methods.Finally,this review offers a personal perspective for future research trends in the development of passivation strategies through inorganic materials.