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The title complex C CrMo3 (μ3-O )3 (μ-O) (μ-O2CCH3 )5 (O2CCH3)3]2Na2 · H2O (Mr=1814. 32) crystallizes in monoclinic, space group P21/ n with a=11.209(5), b=18. 05(1), c=14. 44(1) A , β= 98. 30(5)°. V=2890 (3) A3, Z=2, A = 2. 08 g/cm3, F(000) -1780, Final R = 0. 049, Rw = 0. 058 for 2622 independent reflectons with I>3σ(I). The complex anion contains two Mo3O4 cores which connect two chromium atoms through four μ3-O atoms and eight bridging CH3COO- groups. Each of the Cr atoms and the Mo atoms is coordinated by six oxygen atoms. The anions are linked by Na cations to form one-dimensional infinite chain structure.
The title complex C crystallized in monoclinic space group P21 / n with a = 11.209 (μ-O) 3 (μ-O) (μ-O2CCH3) 5 (O2CCH3) 3] 2Na2 · H2O B = 18.05 (1), c = 14.44 (1) A, β = 98. 30 (5) °. V = 2890 (3) A3, Z = 2, A = 2.08 The complex anion contains two Mo3O4 cores which connect two chromium atoms through four μ3 (g), and the final R = 0. 049, Rw = 0. 058 for 2622 independent reflectons with I> 3σ (I) -O atoms and eight bridging CH3COO- groups. Each of the Cr atoms and the Mo atoms is coordinated by six oxygen atoms. The anions are linked by Na cations to form one-dimensional infinite chain structure.