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用原位红外技术研究了Pd/Al2O3催化CO氧化反应,对CO吸附态的特征以及CO氧化反应中CO和O2的配比进行了试验,获得Pd/Al2O3吸附多重谱带和它在285~373K温区范围内的变化情况。由此证明,Pd与Al2O3发生了相互作用。根据桥型谱带在CO和O2共吸附于不同温度时的变化,确定了转化反应较快的CO和O2配比为2:1。
In-situ infrared technique was used to study the catalytic CO oxidation of Pd / Al2O3. The characteristics of CO adsorption and the CO and O2 molar ratios in CO oxidation were studied. The Pd / Al2O3 adsorption multiple bands were obtained and the results were in the range of 285 ~ 373K Changes in the temperature range. It proves that Pd interacts with Al2O3. According to the changes of the bridge type bands when CO and O2 were co-adsorbed at different temperatures, the conversion ratio of CO to O2 was determined to be 2: 1.