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自兜反应是合成金属硫簇合物的重要方法。本文报道包含ＭＳ４ｍ－（Ｍ＝Ｍｏ，Ｗ，ｍ＝２；Ｍ＝Ｖ，ｍ＝３）的多组分自兜合成体系，讨论了自兜体系组成及各反应物的作用，自兜体系中存在两类化学反应，配位反应和氧化还原反应，基于成簇机理及产物随机分布的讨论，提出了合成体系的某些规律，同时进行合成体系的设计，从中成功地获得新型的金属硫簇合物。
Since the pocket reaction is an important method of synthesis of metal sulfur cluster. In this paper, a multi-component self-pouch system containing MS4m- (M = Mo, W, m = 2; M = V, m = 3) is reported. The composition of the self-pouch system and the effect of each reagent are discussed. There are two types of chemical reactions, coordination reactions and redox reactions. Based on the discussion of the clustering mechanism and the random distribution of products, some rules of the synthesis system are put forward. At the same time, the synthesis system is designed and the new type of metal sulfur clusters Compound.