Synthesis of polycarbonate diol catalyzed by metal-organic framework Zn_4O[CO_2-C_6H_4-CO_2]_3

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：q344494

【摘要】

：

金属器官的框架 Zn4O [1,4-benzenedicarboxylate ] 3 (Zn4O [CO2-C6H4-CO2 ] 3，通常作为 MOF-5 知道，被超声的照耀方法准备。催化剂被 X 光检查衍射(XRD ) 和 Fourier 变换描

【作者】

：

WANG LiPing XIAO Bin WANG Gong

【机构】

：

ChengduInstituteofOrganicChemistry,ChangzhouKeyLaboratoryofGreenandTechnology,GraduateSchoolofChines

【出处】

：

中国科学：化学英文版

【发表日期】

：

2011年9期

【关键词】

：

聚碳酸酯二醇催化剂制备合成金属傅里叶变换红外光谱层状双金属氢氧化物催化活性超声波照射 X射线衍射 metal-organic framework p

【基金项目】

：

supported by the Key Projects in the National Science ＆ Technology Pillar Program during the Eleventh Five-Year Plan Period （2006BAE02B03）, Jiangsu Provincial Science ＆ Technology Pillar Program （BE20

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金属器官的框架 Zn4O [1,4-benzenedicarboxylate ] 3 (Zn4O [CO2-C6H4-CO2 ] 3，通常作为 MOF-5 知道，被超声的照耀方法准备。催化剂被 X 光检查衍射(XRD ) 和 Fourier 变换描绘红外线(FTIR ) 光谱学。它然后经由在 diphenyl 碳酸盐(DPC ) 之间的 transesterification 为聚碳酸酩 diol (PCDL ) 的准备被用作催化剂并且 1， 6-hexandiol (1， 6-HD ) 。它在 tran

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Synthesis of polycarbonate diol catalyzed by metal-organic framework Zn_4O[CO_2-C_6H_4-CO_2]_3

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