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A new compound, bis(tetraunethylcyclopentadienyl)ruthenium has been synthesized by reduction reaction of tetramethylcyclopentadiene, RuCl3 and Zn in situ. The results of X-ray diffraction studies demonstrate the compound to be of a fully eclipsed conformation. The crystal belongs to monoclinic system, space group C2/c with cell parameters a = 22.075(3), b =10.674(3),c=14.135(2) A,β= 101.74(1)°,V = 3261.1A3,Dc=1.4 gcm-3, Z = 8.Several cycles of block matrix least-squares refinement gave the final R = 0.034.
A new compound, bis (tetraunethylcyclopentadienyl) ruthenium has been synthesized by reduction reaction of tetramethylcyclopentadiene, RuCl3 and Zn in situ. The results of X-ray diffraction studies have shown that the compound to be of fully eclipsed conformation. The crystal belongs to monoclinic system, space group C2 / c with cell parameters a = 22.075 (3), b = 10.674 (3), c = 14.135 (2) A, β = 101.74 (1) °, V = 3261.1A3, Dc = 1.4 gcm-3, Z = 8. Volumes of block matrix least-squares refinement gave the final R = 0.034.