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A novel palladium(Ⅱ)complex[(TMEDA)Pd(anca)_2]·2DMSO(1,TMEDA=N,N,N’,N’-tetramethylethylethylenediamine,anca=anthracene-9-carboxylic acid)was synthesized and characterized by single-crystal X-ray diffraction,~1H NMR,UV-Vis and fluorescence spectroscopy.The cell belongs to orthorhombic Aba2 space group with a=19.698(7),b=21.045(7)c=9.062(3)A,Z=4,V=3757(2)A~3,C_(40)H_(46)N_2O_6PdS_2,M_r=821.31,D_c=1.452 g/cm~3,F(000)=1704,the final R=0.0272,wR=0.0667 and GOOF=0.999.Complex 1 exhibits an interesting distorted clip-shaped molecular configuration which is stabilized by intramolecular C-H…O hydrogen bonds.The cells are packed into a 3D supramolecular structure based on the intermolecular C-H…πinteractions which further construct the tubular channels serving as guest molecular channels to include the DMSO solvent molecules inside.Furthermore,the spectroscopic properties of 1 were also investigated.
A novel palladium (Ⅱ) complex [(TMEDA) Pd (anca) _2] · 2DMSO (1, TMEDA = N, N, N’N’-tetramethylethylethylenediamine, anca = anthracene-9-carboxylic acid) single-crystal X-ray diffraction, ~ 1H NMR, UV-Vis and fluorescence spectroscopy. The cell belongs to orthorhombic Aba2 space group with a = 19.698 (7), b = 21.045 (7) c = 9.062 = 4, V = 3757 (2) A ~ 3, C_ (40) H_ (46) N_2O_6PdS_2, M_r = 821.31, D_c = 1.452 g / cm ~ 3, F = 0.0667 and GOOF = 0.999.Complex 1 exhibits an interesting distorted clip-shaped molecular configuration which is stabilized by intramolecular CH ... O hydrogen bonds. The cells are packed into a 3D supramolecular structure based on the intermolecular CH ... πinteractions which further construct the tubular channels serving as guest molecular channels to include the DMSO solvent molecules inside. Futuremore, the spectroscopic properties of 1 were also investigated.