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Crystal structure of the title compound, Cu(phen)(H2O)2· ClO4(phen=1,10 phenanthroline), was determined by X ray crystallography. It crystallizes in the monoclinic system, space group C2/c with lattice parameters a=1.49071(4)nm, b=1.38594(4)nm, c=0.70292(1)nm, β =108.509(1)° and Z=4; The Cu? ion is chelated by a phen ligand and two aqua ligands in cis arrangement and assumes a C2 symmetric square planar geometry with the CuN2O2 core. Eight Cu(phen)(H2O)2· ClO4 molecules are interconnected by strong hydrogen bonds between coordinated water molecules and uncoordinated perchlorate anions to form a molecular scale cavities along c axis. The bond distances of Cu N and Cu O are 0.2003(4)nm and 0.1973(3)nm, respectively. CCDC: 197600.
Crystal structure of the title compound, Cu (phen) (H2O) 2 · ClO4 (phen = 1,10 phenanthroline), was determined by X ray crystallography. It crystallizes in the monoclinic system, space group C2 / c with lattice parameters a = 1.49071 (4) nm, b = 1.38594 (4) nm, c = 0.70292 (1) nm, β = 108.509 (1) ° and Z = 4; The Cu ion is chelated by a phen ligand and two aqua ligands in cis arrangement and assumes a C2 symmetric square planar geometry with the CuN2O2 core. Eight Cu (phen) (H2O) 2 · ClO4 molecules are interconnected by strong hydrogen bonds between coordinated water molecules and uncoordinated perchlorate anions to form a molecular scale cavities along the c axis. The Bond distances of Cu N and Cu O are 0.2003 (4) nm and 0.1973 (3) nm, respectively. CCDC: 197600.