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通过一系列滴定量热测定,求得了298.15K时十二钨硅酸及其6DMF、8DMSO加合物的标准生成焓,其数值分别为-(13.14±0.01)×103KJ·mol-1、-(13.61±0.01)×103KJ·mol-1及-(13.86±0.01)×103KJ·mol-1.
Through a series of titration calorimetry, the standard enthalpies of formation of dodecenyl tungstosilicic acid and their 6DMF and 8DMSO adducts at 298.15K were obtained and their values were - (13.14 ± 0.01) × 103KJ · mol -1, - (13.61 ± 0.01) × 103KJ · mol-1 and - (13.86 ± 0.01) × 103KJ · mol-1, respectively.