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本文介绍了用于分析游离基反应的前线轨道的微扰分子轨道理论的普通方程。从而用微扰分子轨道理论半定量地解释了脂肪族的游离基取代和芳香族的游离基取代反应的反应性和选择性。
This article presents the general equations for the theory of perturbed molecular orbital for the analysis of the frontier orbit of radical reactions. Thus, the reactivity and selectivity of aliphatic radical substitution and aromatic radical substitution reaction are semi-quantitatively explained by perturbation molecular orbital theory.