含铜蒸汽转化催化剂的应用基础研究

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应用程序升温还原法(TPR),X—光衍射分析法(XRD),微反色谱法(MRC)和气氛热重法(ATGA),比较系统地研究了铜对制氢催化剂还原性、活性和抗碳性的影响。从TPR曲线随铜的加入量和加入方法变化的规律,铜对还原活化能的影响,镍晶格参数随铜含量的变化以及铜钯作用的对比等实验结果,提出了铜促进还原作用的机理和模型,相当满意地解释了已有的实验结果。
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