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The new compound, Ni(TSSB)(Phen)(H2O)·4H2O (TSSB=Taurine Salicylic Schiff Base, phen=O- Phenanthroline) has been synthesized and characterized by IR, elemental analysis and X-ray diffraction. The compound crystal data: triclinic, space group P1, a=1.0497(2), b=1.1225(2), c=2.3843(4) nm, α=87.676(3)°, β= 82.957(3)°, γ=62.924(3)°; V=2.482 3(7) nm3, Z=4; Dc=1.488 g·cm-3, μ=0.920 mm-1, F(000)=1 160, Goof=1.032, (Δρ)max=899 e·nm-3, (Δρ)min=- 624 e·nm-3. The compound is a dimmer. In the complex, two Ni! were coordinated by three oxygen atoms and three nitrogen atoms while the O atoms of Ac- groups did not coordinate. The Ni! formed a distorted octahedron geometry. The compound is an three dimensional net connecting with hydrogen bonding. CCDC: 275474. The TG-IR of the complex was analyzed. The kinetics of the thermal decomposition reaction of the complex was studied under a non isothermal condition by TG-IR. TG and DTG curves indicate that the complex decom- posed in four stages: Ni(TSSB)(phen)H2O·4H2O Ni(TSSB)(phen)H2O Ni(TSSB)(phen) Ni(TSSB) NiO
The new compound, Ni (TSSB) (Phen) (H2O) · 4H2O (TSSB = Taurine Salicylic Schiff Base, phen = O- Phenanthroline) has been synthesized and characterized by IR, elemental analysis and X-ray diffraction : triclinic, space group P1, a = 1.0497 (2), b = 1.1225 (2), c = 2.3843 (4) nm, α = 87.676 (3) °, β = 82.957 ); V = 2.482 3 (7) nm3, Z = 4; Dc = 1.488 g · cm-3, μ = 0.920 mm- 1, F (000) = 1 160, Goof = 1.032, (Δρ) max = 899 e · nm-3, (Δρ) min = -624 e · nm-3. The compound is a dimmer. In the complex, two Ni! were coordinated by three oxygen atoms and three nitrogen atoms while the O atoms of Ac-groups The non-coordinate. The Ni! formed a distorted octahedron geometry. The compound is an three dimensional net connecting with hydrogen bonding. CCDC: 275474. The TG-IR of the complex was analyzed. The kinetics of the thermal decomposition reaction of the complex was studied under a non isothermal condition by TG-IR. TG and DTG curves indicate that the complex decomposed in four stag (phen) Ni (TSSB) (phen) H 2 O · 4H 2 O (TSSB) (phen) H 2 O