Steric Effect Modulating the Structures of Trinuclear Zinc Carboxylate Frameworks

• 作 者: SUN Yun-Kai XIE Rui WANG Xiao-
• 机 构: SchoolofChemistryandChemicalEngineering,LaboratoryofProteinStructureandFunction
• 出 处: 结构化学
• 发表日期: 2016年9期
• 关键词: 空间位阻效应 框架结构 羧酸锌 X射线衍射分析 Π-Π堆积作用 三环 次级结构单元 芳香族羧酸 zinc（Ⅱ） metal-carboxylate framew
• 基金项目: supported by the National Natural Science Foundation of China（No.11375082,11305086,11175080）,Science Foundation of Hunan Province Department of Education（No.12A117）,the Project Sponsored by the Scient

By the reaction of different aromatic dicarboxylic acid with zinc nitrate, three metal-carboxylate frameworks, [Zn3（BDC）3（EtOH）2]（1）, [Zn3（BDC）3（py）2]·2DMF（2）, and [Zn3（NH2-BDC）3（H2O）2]·5DMF（3） which are constructed on the same linear trinuclear