钴、镍与α-萘乙酸配合物的合成与表征

• 作 者: 唐定兴 张德 赵虎
• 机 构: 安徽机电学院生物化学工程系!安徽芜湖241000,青海师范大学测试中心!青海西宁810008,青海师范大学测试中心!青海西宁810008
• 出 处: 化学研究与应用
• 发表日期: 2000年03期
• 关键词: 钴配合物 镍配合物 α-萘乙酸 α-呋喃甲醛肟

The binary complexes of Co +2 ,Ni +2 with α naphthaleneacetate(L) were prepared by the reaction of MCO 3(M=Co,Ni) with HL or by the extraction of the mixture of NiCl 2 and NaL with CHCl 3 in aqueous solution.The ternary complexes of Co +2 ,Ni +2 with α naphthaleneacetate and α furfuraloxime(L’) were prepared by the reaction of NiCl 2,NaL and L’.The complexes were investigated by elementary analysis,molar conductivity,IR and UV techniques.

The binary complexes of Co +2, Ni +2 with a naphthalene acetate (L) were prepared by the reaction of MCO 3 (M = Co, Ni) with HL or by the extraction of the mixture of NiCl 2 and NaL with CHCl 3 in aqueous solution. The ternary complexes of Co +2, Ni +2 with α naphthalene acetate and α furfuraloxime (L ’) were prepared by the reaction of NiCl 2, NaL and L’. The complexes were investigated by elementary analysis, molar conductivity, IR and UV techniques.