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采用水热合成方法合成了1种Zn(Ⅱ)配位聚合物{[Zn(C4H4O6)(H2O)2]·2H2O}n,对该化合物的单晶进行了X-射线衍射分析,确定了结构.标题化合物是由酒石酸根作为六齿配体与Zn(Ⅱ)离子进行配位形成的具有3D无限结构的配位聚合物.同时对化合物的紫外-可见-近红外光谱、红外光谱及荧光光谱进行了测定及分析.
A Zn (Ⅱ) coordination polymer {[Zn (C4H4O6) (H2O) 2] · 2H2O} n was synthesized by hydrothermal method. The single crystal of this compound was characterized by X-ray diffraction. . The title compound is a 3D-infinite coordination polymer formed by the coordination of tartrate as a hexadentate ligand with Zn (II) ions. The UV-Vis-NIR, IR and fluorescence spectra The measurement and analysis were carried out.