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基于对 8种中国生物质材料非等温热分解的实验结果和动力学分析 ,发现分别源于生物质样品变动和动力学模型变动的表观热解动力学参数 ,即表观活化能E和指前因子A ,满足动力学补偿效应关系。详细讨论了鉴别真、假动力学补偿效应的定量统计判据
Based on the experimental results and kinetic analysis of non-isothermal pyrolysis of eight Chinese biomass materials, it was found that the apparent pyrolysis kinetic parameters derived from the variation of the biomass sample and the kinetic model respectively, that is, the apparent activation energy E and The pre-factor A satisfies the kinetic compensation effect. The quantitative statistical criteria for the identification of true and pseudodynamic compensation effects are discussed in detail