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由于含氟聚合物的特性和重要性,含氟单体的辐射聚合已成为辐射聚合的一个独立的部分。六十年代以来几乎研究过各种氟烯单体的聚合及共聚合。 通过广泛研究,逐步了解了氟烯烃单体辐射聚合的特征,明确了聚合机构,以及得到了一些很有工业化希望的聚合工艺过程。本文仅这几方面,结合我们(上海化工研究院)的研究工作,进行一些讨论。
Due to the nature and importance of fluoropolymers, radiation polymerization of fluoromonomers has become an independent part of the radiation polymerization. Almost all the polymerization and copolymerization of various fluoroolefin monomers have been studied since the 1960s. Through extensive research, we gradually understand the characteristics of radiation polymerization of fluoroolefin monomer, clear the polymerization mechanism, and obtained some very promising industrial polymerization process. This article only in these areas, combined with our (Shanghai Chemical Industry Research Institute) research work, to conduct some discussions.