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水溶液溶质分子辐射分解机构的研究,是水溶液辐射化学基本理论之一。本文研究高氯酸水溶液的辐射分解。由于高氯酸根与金属离子的络合能力很小,通常在高氯酸水溶液中进行金属离子辐照效应的研究。因此在研究金属离子辐照效应的同时,也必须研究高氯酸根的辐解效应。由于氯原子的多价性,故可求出不同产物的产额分布“谱”,为研究辐解机构提供丰富的实验数据。根据文献[1][2],高氯酸水溶液在辐照时,氯酸根形成
Aqueous solute molecular radiation decomposition mechanism, is one of the basic theory of aqueous solution of radiation chemistry. This paper studies the perchloric acid aqueous solution of radiation decomposition. Due to the low ability of complexation of perchlorate with metal ions, the effect of metal ion irradiation is usually studied in perchloric acid aqueous solution. Therefore, in studying the metal ion irradiation effect, we must also study the radiolysis effect of perchlorate. Due to the polyvalent nature of chlorine atoms, the “spectrum” of the yield distribution of different products can be obtained, providing abundant experimental data for the study of radiolytic mechanisms. According to the literature [1] [2], perchlorate aqueous solution formed, chlorate formation