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The manganese(II) complex, [Mn(phen)2(4-CPOA)(H2O)]?5H2O (4-CPOAH2 = 4- carboxyphenoxyacetic acid) has been synthesized and characterized by elemental analyses, IR, TG and single-crystal X-ray diffraction. The crystal is of monoclinic, space group C2/c, with a = 27.471(3), b = 18.490(4), c = 14.507(3) ?, β = 115.13(3)o, V = 6671(3) ?3, Z = 8, Mr = 717.58, Dc= 1.429 g/cm3, μ = 0.462 mm–1, F(000) = 2984, the final R = 0.0535 and wR = 0.1200 for 5413 observed reflections with I > 2σ(I). The Mn(II) atom is coordinated by one O atom of 4-carboxy- phenoxyacetate, four N atoms of two 1,10-phenanthroline and one water molecule, residing in a distorted octahedral environment. A supramolecular network structure is formed by hydrogen bonds and π-π stacking interactions.
The manganese (II) complex, [Mn (phen) 2 (4-CPOA) (H2O)] 5H2O (4-CPOAH2 = 4- carboxyphenoxyacetic acid) has been synthesized and characterized by elemental analyzes, IR, TG and single-crystal X-ray diffraction. The crystal is of monoclinic space group C2 / c with a = 27.471 (3), b = 18.490 (4), c = 14.507 (3) 6671 (3)? 3, Z = 8, Mr = 717.58, Dc = 1.429 g / cm3, μ = 0.462 mm- 1, F (000) = 2984, the final R = 0.0535 and wR = 0.1200 for 5413 observed reflections with I> 2σ (I). The Mn (II) atom is coordinated by one O atom of 4-carboxy-phenoxyacetate, four N atoms of two 1,10-phenanthroline and one water molecule, residing in a distorted octahedral environment. A supramolecular network structure is formed by hydrogen bonds and π-π stacking interactions.