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采用溶胶──凝胶水热晶化合成法;以钼和磷作为骨架原子合成出一种新型磷钼酸盐微孔晶体化合物.使名为MP-C(MP代表磷钼酸盐,C代表中国).单晶结构研究表明标题化合物具有层状结构.结构基元是磷氧四面体和钼氧八面体以氧桥形式连成的多元孔系,层间以氢键相连,晶体属于单斜晶系,P2_1/n空间群.最终偏离因子R=0.028.
Sol-gel hydro-thermal crystallization method was used to synthesize a new type of phosphomolybdate microporous crystal compound using molybdenum and phosphorus as skeleton atoms. Make the name MP-C (MP for phosphomolybdate, C for China). Single crystal structure studies show that the title compound has a layered structure. The structural motif is a multi-pore system in which oxyphosphine tetrahedra and molybdate octahedra are connected by an oxygen bridge and are connected by hydrogen bonds. The crystal belongs to the monoclinic space group P2_1 / n. The final deviation factor R = 0.028.