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SC(Ph)NHPh,CuX(X=Cl,Br,I)和PPh_3的固相反应产物经CS_2处理得红黄色立方晶体[Cu(SC(Ph)NHPh)(PPh_3)_2X],其中X=Cl的单晶用X射线衍射法收集晶胞参数,此晶体属单斜晶系,空间群P2_1/c,α=1.8013(5)nm,b=1.4588(5)nm,c=1.7222(4)nm,β=105.54(3)°,F=4.3601nm~3,Z=4。中心铜离子以扭曲四面体配位,Cu原子周围的平均键角为109.4°,其中Cu—S键、Cu—Cl键、Cu—P(1)键和Cu—P(2)键的键长分别为0.2352(3)nm、0.2375(4)nm、0.2297(4)nm和0.2282(3)nm.
The solid reaction products of SC (Ph) NHPh, CuX (X = Cl, Br, I) and PPh_3 were treated by CS_2 to get the red and yellow cubic crystal [Cu (SC (Ph) NHPh) (PPh_3) _2X] Of the crystal was collected by means of X-ray diffraction. The crystal belongs to the monoclinic system with space group P2_1 / c, α = 1.8013 (5) nm, b = 1.4588 (5) nm, c = 1.7222 , β = 105.54 (3) °, F = 4.3601 nm-3, and Z = 4. The center copper ion coordinates with twisted tetrahedron. The average bond angle around Cu atom is 109.4 °. The bond length of Cu-S bond, Cu-Cl bond, Cu-P (1) bond and Cu-P 0.2352 (3) nm, 0.2375 (4) nm, 0.2297 (4) nm and 0.2282 (3) nm, respectively.