STUDIES ON CYCLOPENT-2-ENONE: (Ⅲ) THE STUDY ON DECONJUGATION OF CYCLOPENT -2-ENONE ALDOL ADDUCTS

• 作 者: M.M.Campbell D.W.Brown
• 机 构: SchoolofChemistryUniversityofBath,U.K.,SchoolofChemistry,UniversityofBath
• 出 处: Chinese Chemical Letters
• 发表日期: 1991年10期
• 关键词: DESIRED ATTEMPTED explained subsequent SILANE adding lithium illust aldehyde 坠山

Deconjugation of cyclopent-2-enone aldols were attempted under various conditions, and the desired deconjugated product was achieved via dianion approach. Various results obtained in this study are explained by structure and transition state analysis.