Mercury removal performance over a Ce-doped V-W/TiO2 catalyst in an internally illuminated honeycomb

来源 :中国科学:技术科学(英文版) | 被引量 : 0次 | 上传用户:popularmp3007008
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A new type of internally illuminated honeycomb photoreactor was designed.The honeycomb catalyst prepared by using Ce-doped TiO2 with 1%-2% vanadium and tungsten was employed for mercury removal from simulated industrial flue gas.The adsorption kinetics in the reaction process were studied.The results showed that the internally illuminated honeycomb pho-toreactor had good mercury removal performance.When the temperature was 25℃ and the ultraviolet (UV) light intensity reached 80 μW/cm2,the mercury removal efficiency reached 92.5%.The mercury removal efficiency increased significantly with the doping ratio of Ce.XPS analysis showed that the oxidation state of Ce changed from 4 to 3 in the mercury removal reaction and produced lattice oxygen,which acts as an oxidant.O2 can promote mercury removal by honeycomb catalysts;SO2 and HC1 also had positive effects,while NO had an inhibitory effect on mercury removal.Kinetic research in the reaction process showed that the quasi-first-order dynamic model had good fitting results,and the correlation coefficients of the fitting results for multiple sets of experimental data were more than 0.999.
其他文献
候选门级辐射类群(candidate phyla radiation,CPR)所包含的细菌种类约占已知细菌种类总数的1/4,然而该类细菌中只有解糖微小寄生菌(Saccharibacteria,又名TM7)的少数菌株被成功分离培养.研究发现,解糖微小寄生菌具有许多独特的生物学性状:该类细菌需要寄生在宿主细菌表面生长,这是一种全新的“细菌-细菌”寄生生存方式;细菌尺寸及基因组均较小,缺乏代谢相关基因,不能合成氨基酸和维生素;对宿主细菌表现出杀伤作用或保护其躲避免疫系统的攻击.此外,解糖微小寄生菌与牙周病等疾病
Atomic layer deposition (ALD) as a flexible surface-controlled fabrication technique has attracted widespread interest in numerous nanotechnology applications,which can obtain ultrathin or two-dimensional molybdenum disulfide (2D MoS2) films.The ALD techn
The safety of lithium-ion batteries under mechanical abuse has become one of the major obstacles affecting the development of electric vehicles.In this paper,the lithium-ion battery safety model under mechanical abuse conditions is proposed by the Back Pr
A segmented hyper-redundant manipulator can perform complicated operation tasks in a confined space due to its high flexibility and dexterity.However,the trajectory planning in a narrow space and obstacles environment is very challenging for the manipulat
Wearable pressure sensors have drawn significant attention because of their extensive applications in motion detection,tactile sensing,and health monitoring.However,the complex manufacturing process and high cost of active materials make low-cost,large-sc
This paper proposes a novel motion planning and tracking framework based on improved artificial potential fields (APFs) and a lane change strategy to enhance the performance of the active collision avoidance systems of autonomous vehicles on structured ro
The widely used kinesthetic demonstration method of dragging robotic manipulators cannot obtain reliable information for autonomous robot manipulation because an additional external force rather than pure contact force will be reflected on the force senso
Station-keeping (SK) is indispensable in actual geostationary (GEO) satellite missions.Due to the luni-solar gravity perturba-tions,the inclination of a GEO satellite suffers the issues of secular drift and long-period oscillation.Current north-south (NS)
A numerical simulation method of shield tunnel excavation is developed to capture the time-dependent deformation behaviour of surrounding soil.The simulation method consists of four parts:(i) an elastic-plastic-viscous constitutive model that can not only
With the development of electric vehicles (EV),there is a huge demand for electric vehicle charging stations (EVCS).The utilization of renewable energy sources (RES) in EVCS can not only decrease the energy fluctuation by participating in peak-load reduct