【摘 要】
:
A new cluster compound {[Mo3(μ3-O)(μ-S)3(dtp)3(py)3][CdI(dtp)2]} (dtp=S2P(O-was obtained from the reaction of (Mo3OS3(dtp)4(H2O)] with a CdI2-Bu4NI mixture.T
【出 处】
:
Chinese Journal of Chemistry
论文部分内容阅读
A new cluster compound {[Mo3(μ3-O)(μ-S)3(dtp)3(py)3][CdI(dtp)2]} (dtp=S2P(O-was obtained from the reaction of (Mo3OS3(dtp)4(H2O)] with a CdI2-Bu4NI mixture.The molecular structure is composed of a cluster cation [Mo3OS3(dtp)3(py)3]+ and the complex anion [CdI(dtp)2]-Crystal data:Triclinic,space group P1 with cell parameters a=1.4672(7),b=1.5356(5),c=1.6806(5) nm,α=74.59(3),β=67.89(4),7=78.86(3)°,V=3.364(2) nm3,and Z=2,least-squares refinement of 8941 reflections gives a final agreement factor of R=0.052,Rw=0.065.
A new cluster compound {[Mo3 (μ3-O) (μ-S) 3 (dtp) 3 (py) 3] [CdI (dtp) 2]} (dtp = S2P (dtp) 4 (H2O)] with a CdI2-Bu4NI mixture. The molecular structure is composed of a cluster cation [Mo3OS3 (dtp) 3 (py) 3] + and the complex anion [CdI (dtp) 2] : Triclinic, space group P1 with cell parameters a = 1.4672 (7), b = 1.5356 (5), c = 1.6806 (5) nm, α = 74.59 (3), β = 67.89 (4), 7 = 78.86 ) °, V = 3.364 (2) nm3, and Z = 2, least-squares refinement of 8941 reflections gives a final agreement factor of R = 0.052, Rw = 0.065.
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