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采用计算振动频率与观测值相拟合的方法,对N-甲基甲酰胺和乙酰胺分别优化了一套振动力场校正因子;研究了这些校正因子在酰胺系列分子中的可迁性。
A set of vibration force field correction factors for N-methylformamide and acetamide were optimized respectively by the method of calculating the vibration frequency and the observed value. The migration of these correction factors in the amide series molecules was studied.