【摘 要】
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UHF/AM1 method has been applied to study the thermolyses of o-aminobenzoyl, o-amino-p-methylbenzoyl, o-amino-p-formalbenzoyl azides. The results obtained show t
【机 构】
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江西师范大学化学系!南昌330027,江西师范大学化学系!南昌330027,江西师范大学化学系!南昌330027,江西师范大学化学系!南昌330027
论文部分内容阅读
UHF/AM1 method has been applied to study the thermolyses of o-aminobenzoyl, o-amino-p-methylbenzoyl, o-amino-p-formalbenzoyl azides. The results obtained show that these reactions proced through various competing routes yielding to different products, and the activation energy of the rate-determining steps of routes (2)—(4) are lower than that of route(1).
UHF / AM1 method has been applied to study the thermolyses of o-aminobenzoyl, o-amino-p-methylbenzoyl, o-amino-p-formalbenzoyl azides. The results obtained show that these reactions through various competing routes yielding to different products, and the activation energy of the rate-determining steps of routes (2) - (4) are lower than that of route (1).
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