Effects of Electron Donor and Different Solvents on Polarizability and Second Hyperpolarizability of

• 作 者: LIU Hai-bo QIU Yong-qing YANG
• 机 构: InstituteofFunctionalMaterialChemistry
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2012年2期
• 关键词: 二阶超极化率 四氯化碳溶剂 电子供体 铝 镓 水分子 氧原子 系统调查 Polarizability Second hyperpolarizability Di
• 基金项目: Supported by the National Natural Science Foundation of China（No.20873017）, the Natural Science Foundation of Jilin Province China（No.20101154）

The polarizability(α) and second hyperpolarizability(γ) were systemically investigated for singlet diradical complex involving X(X=B,Al,Ga) atom.The results show that both the α and γ can be effectively tuned by varying the distance R(between compound A a