Synthesis and structure of a novel MoFe_4S_4 cubane-like cluster (Me_3PhCH_2N)_2[MoFe_4S_4(SC_6H_(

• 作 者: 陈昌能 邓玉恒 洪茂椿 温庭斌 张纯喜 刘秋田 卢嘉锡 陈小明 康北笙 周忠远 麦松威
• 出 处: Science in China(Series B)
• 发表日期: 1998年03期

A novel (Me 3PhCH 2N) 2[MoFe 4S 4(SC 6H 11 ) 7] cubane like cluster was obtained from a reaction system including (NH 4) 2MoS 4, FeCl 2 and NaSC 6H 11 in methanol, and characterized by X ray crystallography. The title compound crystallizes in triclinic space group P 1 with a =1.523 1(3), b =1.610 5(3), c =1.838 3(4) nm, α =77.18 (3)°, β =75.17(3)°, γ =64.60 (3)°, and Z =2. Also included in this paper are the discussions on the variation of the reaction products obtained from the participation of cyclohexylthiolate and on the changes of the structural features of the products.

A novel (Me 3 PhCH 2 N) 2 [MoFe 4S 4 (SC 6H 11) 7] cubane like cluster was obtained from a reaction system including (NH 4) 2MoS 4, FeCl 2 and NaSC 6H 11 in methanol, crystallography. The title compound crystallizes in triclinic space group P 1 with a = 1.523 1 (3), b = 1.610 5 (3), c = 1.838 3 3) °, γ = 64.60 (3) °, and Z = 2. Also included in this paper are the discussions on the variation of the reaction products obtained from the participation of cyclohexylthiolate and on the changes of the structural features of the products.